Developing a Thermodynamical Method for Prediction of Activity Coefficient of TBP Dissolved in Kerosene

Results of the experimental measurements on the partial molar volume of kerosene used as a medium for dissolving TBP are utilized to determine the activity of TBP in the binary kerosene-TBP solution through the application of Gibbs-Duhem equation. The treatment is based on combination of the experimental data with the thermodynamic values available on the compressibility factor of pure kerosene at room temperature. It is shown that the activity of TBP in kerosene has a positive deviation from ideality with an activity coefficient derived as follows:1) at X TBP ≤ 0.01: γ TBP = 42.530, 2) at the 0.01 X TBP 0.2: 3) at the higher TBP concentrations 0.2 X TBP 0.97: and 4) at TBP Raoultian concentrations 0.97 ≤ X TBP:γ TBP = 1. These quantities can be utilized at temperature closed to 298 K.

McCabe-Thiele plot for stripping of manganese loaded D2EHPA using

Water adsorption in the organic phase for the D2EHPA-kerosene

Solvent Extraction of Nickel and Zinc from Nitric Acid Solution

Water adsorption in the organic phase for the D2EHPA-kerosene

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Solvent Extraction of Nickel and Zinc from Nitric Acid Solution Using D2EHPA: Experimental and Modeling

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Separation of Re and Mo from Roasting-Dust Leach-Liquor Using

Separation of Re and Mo from Roasting-Dust Leach-Liquor Using

PDF) Solvent Extraction: Classical and Novel Approaches This page intentionally left blank Solvent Extraction: Classical and Novel Approaches

Solvent Extraction of Nickel and Zinc from Nitric Acid Solution Using D2EHPA: Experimental and Modeling

Separation of Re and Mo from Roasting-Dust Leach-Liquor Using

Kinetic features of solvent extraction by N,O-donor ligands of f-elements: a comparative study of diamides based on 1,10-phenanthroline and 2,2′-bipyr - Physical Chemistry Chemical Physics (RSC Publishing) DOI:10.1039/D3CP05081E

Developing a Thermodynamical Method for Prediction of Activity Coefficient of TBP Dissolved in Kerosene

Developing a Thermodynamical Method for Prediction of Activity